3 years ago

Radical Decarboxylation/Annulation of Acrylamides with Aliphatic Acyl Peroxides

Radical Decarboxylation/Annulation of Acrylamides with Aliphatic Acyl Peroxides
Changduo Pan, Qingting Ni, Jin-Tao Yu, Yu Fu
A radical decarboxylation/annulation of acrylamides with aliphatic acyl peroxides was developed, giving a series of linear alkylated oxindoles in moderate to good yields. The reaction used aliphatic acyl peroxides as the linear alkyl radical source and tolerated a broad scope of substrates under metal-free conditions, offering a simple and efficient approach toward alkylated oxindoles.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b00663

DOI: 10.1021/acs.joc.7b00663

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