Crystal Growth & Design
Crystal Growth & Design
3 years ago

Structural Diversity, Magnetic Properties, and Luminescent Sensing of the Flexible Tripodal Ligand of 1,3,5-Tris(4-carbonylphenyloxy)benzene Based Mn(II)/Cd(II) Coordination Polymers

Structural Diversity, Magnetic Properties, and Luminescent Sensing of the Flexible Tripodal Ligand of 1,3,5-Tris(4-carbonylphenyloxy)benzene Based Mn(II)/Cd(II) Coordination Polymers
Kegong Fang, Tuoping Hu, Xiaoqing Wang, Jie Zhang, Liming Fan, Liangqin Huo
On the basis of the flexible tripodal ligand of 1,3,5-tris(4-carbonylphenyloxy)benzene, four three-dimensional (3D) Mn(II)/Cd(II) coordination polymers have been obtained with the structure ranging from a 3D (4,8)-connected flu net, 3D 12-connected {312.440.512.62} net, 2-fold interpenetrated 3D (3,8)-connected tfz-d net, to 3D (3,7)-connected {4.62}{47.614} net. The magnetic measurements indicate that 1 and 3 have antiferromagnetic exchange interactions between the adjacent MnII ions of the SBUs. And the fluorescence measurements show 2 and 4 exhibit highly sensitive and selective detection for Cr3+ cation and nitrobenzene derivatives (nitrobenzene, p-nitrotoluene, p-nitroaniline, and p-nitrophenol).

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00986

DOI: 10.1021/acs.cgd.7b00986

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