3 years ago

Exploration of a Variety of Copper Molybdate Coordination Hybrids Based on a Flexible Bis(1,2,4-triazole) Ligand: A Look through the Composition-Space Diagram

Exploration of a Variety of Copper Molybdate Coordination Hybrids Based on a Flexible Bis(1,2,4-triazole) Ligand: A Look through the Composition-Space Diagram
Silvio Decurtins, Harald Krautscheid, Andrey B. Lysenko, Stefan Henfling, Oliver Erhart, Karl W. Krämer, Konstantin V. Domasevitch, Shi-Xia Liu, Eduard B. Rusanov, Ganna A. Senchyk
Flexible 1,3-bis(1,2,4-triazol-4-yl)propane (tr2pr), adopting several favorable conformations (anti/anti, anti/gauche, and gauche/gauche), offers a wide choice for metal−ligand interactions resulting in a variety of CuI/MoVI and CuII/MoVI coordination hybrids. Nine coordination polymers of diverse architectures were developed in the Cu(OAc)2/tr2pr/(NH4)6Mo7O24 system by employing hydrothermal crystallization utilizing the composition space diagram approach.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01735

DOI: 10.1021/acs.inorgchem.7b01735

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