Inorganic Chemistry
Inorganic Chemistry
3 years ago

Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism

Triaryl-Boron Functionalized Dinuclear Platinum Complexes Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism
Nan Wang, Mingfeng Hu, Suning Wang, Françoise Sauriol, Soren K. Mellerup, Xiang Wang, Tai Peng
A series of triarylboron-functionalized Pt(II) dinuclear complexes using a photoactive bis(4-pyridyl)ethylene (bpe) bridging unit has been found to display cis- and trans-isomerism in a crystal state and in solution. Light can be used to drive the cis- and trans-isomerization process with the trans-isomer being the dominant species in solution.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01535

DOI: 10.1021/acs.inorgchem.7b01535

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