4 years ago

Platinum Complexes of N,N′,N″,N‴-Diboronazophenines

Platinum Complexes of N,N′,N″,N‴-Diboronazophenines
Hu Lei, Shawkat M. Aly, Paul-Ludovic Karsenti, Pierre D. Harvey, Daniel Fortin
Linking four trans-ArC≡CPt(PR3)2C≡C arms (Ar = C6H5, R = Et; Ar = hexa(n-hexyl)truxene, R = Bu) onto the non-emissive azophenine along with its cyclization by two difluoroboranes (BF2+) renders the central core fluorescent in the near-IR region.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01942

DOI: 10.1021/acs.inorgchem.7b01942

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