3 years ago

Imaging the halogen bond in self-assembled halogenbenzenes on silver

Zhumin Han, Ruqian Wu, Peter J. Wagner, Xinyuan Wei, W. Ho, Chi-lun Chiang, Yanxing Zhang, Chen Xu, Gregory Czap

Halogens are among the most electronegative elements, and the variations in size and polarizability of halogens require different descriptions of the intermolecular bonds they form. Here we use the inelastic tunneling probe (itProbe) to acquire real-space imaging of intermolecular-bonding structures in the two-dimensional self-assembly of halogenbenzene molecules on a metal surface. Direct visualization is obtained for the intermolecular attraction and the "windmill" pattern of bonding among the fully halogenated molecules. Our results provide a hitherto missing understanding of the nature of the halogen bond.

Publisher URL: http://science.sciencemag.org/cgi/content/short/358/6360/206

DOI: 10.1126/science.aai8625

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