Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [([small kappa]3-tmps)(CO)2Nb[triple bond, length as m-dash]E-R] (E = Si, Ge, Sn; tmps = MeSi(CH2PMe2)3; R = aryl)

5 years ago

Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [([small kappa]3-tmps)(CO)2Nb[triple bond, length as m-dash]E-R] (E = Si, Ge, Sn; tmps = MeSi(CH2PMe2)3; R = aryl)

Alexander C. Filippou, David Hoffmann, Gregor Schnakenburg

A systematic, efficient route to the first heavier tetrylidyne complexes of niobium [([small kappa]³-tmps)(CO)₂Nb[triple bond, length as m-dash]E-R] (E = Si-Sn; R = aryl) starting from the carbonyl niobate (NMe₄)[Nb(CO)₄([small kappa]²-tmps)] is presented.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/kSMSeQPPs28/C7SC02708G

DOI: 2017/SC/C7SC02708G

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