Journal of Organic Chemistry
Journal of Organic Chemistry
5 years ago

Total Synthesis of Avrainvilleol

Total Synthesis of Avrainvilleol
Kenneth A. Miller, Aaron Wegener
The first total synthesis of the marine natural product avrainvilleol is reported. The total synthesis features the first application of the transition-metal-free coupling of a tosyl hydrazone and a boronic acid to the preparation of a complex natural product, and the first example of this coupling with a hindered diortho substituted hydrazone substrate.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b02028

DOI: 10.1021/acs.joc.7b02028

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