3 years ago

Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds

Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds
Hoda Keipour, Thierry Ollevier
An efficient iron-catalyzed carbene insertion reaction of α-diazo carbonyl compounds into the Si–H bond was developed. A wide range of α-silylesters was obtained in high yields (up to 99%) from α-diazoesters using a simple iron(II) salt as catalyst.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02488

DOI: 10.1021/acs.orglett.7b02488

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