Inorganic Chemistry
Inorganic Chemistry
3 years ago

Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation

Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation
Brian K. Breedlove, Yusuke Horie, Yoji Horii, Keiichi Katoh, Masahiro Yamashita
Structures and single-molecule magnet (SMM) properties of protonated/deprotonated terbium(III) phthalocyaninato double-decker complexes were investigated. Structural analysis revealed that protonated double-decker complex (1H) adopts unsymmetrical structure, whereas deprotonated one (1−) shows symmetrical windmill-like distortion. Detailed magnetic analysis revealed that SMM properties of 1− are superior as compared to those of 1H. These results demonstrated the manipulation of SMM properties through protonation/deprotonation.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02124

DOI: 10.1021/acs.inorgchem.7b02124

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.