3 years ago

Proton-Coupled O-Atom Transfer in the Oxidation of HSO3– by the Ruthenium Oxo Complex trans-[RuVI(TMC)(O)2]2+ (TMC = 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane)

Proton-Coupled O-Atom Transfer in the Oxidation of HSO3– by the Ruthenium Oxo Complex trans-[RuVI(TMC)(O)2]2+ (TMC = 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane)
Kai-Chung Lau, Qian Wang, William W. Y. Lam, Hong Yan Zhao, Po-Kam Lo, Tai-Chu Lau
The proposed mechanism for the oxidation of HSO3 by a ruthenium(VI) dioxo complex involves concerted or stepwise proton-coupled O-atom transfer.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02509

DOI: 10.1021/acs.inorgchem.7b02509

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