3 years ago

Three in One Crystal: the Coordination Diversity of Zinc Polypyridine Complexes

Cui Wang, Johannes Moll, Daniel Geißler, Sven Otto, Katja Heinze, Christoph Förster, Ute Resch-Genger
The synthesis, structural and photophysical properties of two novel zinc(II) complexes bearing the tridentate ddpd (N,N' dimethyl N,N' dipyridin 2 ylpyridine 2,6 diamine) ligand are presented. Structural investigations have been carried out by single crystal X-ray diffractometry, NMR spectroscopy and Density Functional Theory calculations, revealing a diverse coordination behavior depending on the counter ion. Spectroscopic (UV-VIS and emission spectroscopy) and theoretical techniques (density functional theory and time dependent DFT calculations) have been employed to explore the photophysical properties of the complexes.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejic.201700948

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