4 years ago

Mechanosynthesis of second sphere coordination salts and chelating complexes: structures, reversible transformations, and nitroaromatic explosives sensoring

Wen-long Duan, Fang Guo, Hai-tao Li
We have investigated the mechanosynthesis of a series of second-sphere salts (guest⊂ [H2L]2+*[MCl4]2−) and the reversible transformations with their chelating coordination complexes [MCl2(L)], via dehydrochlorination reaction, L = N,N′-dibenzyl-(±)-trans-1,2-diaminocyclohexane. The second-sphere salts and their corresponding coordination complexes show different solid state fluorescence spectra. The complex (ZnCl2)(L)(2′) can act as a fluorescent sensor for highly sensitive detection of nitroaromatic compounds through fluorescence quenching.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejic.201700659

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