Inorganica Chimica Acta
Inorganica Chimica Acta
3 years ago

1,10-Phenanthroline based colorimetric and fluorescent sensor for Hg2+ in water: Experimental and DFT study

1,10-Phenanthroline based colorimetric and fluorescent sensor for Hg2+ in water: Experimental and DFT study
A novel colorimetric probe (L) was prepared and its metal ion sensing properties were investigated. Probe L exhibited obvious colorimetric response toward Hg2+ in water. The association constant for probe L-Hg2+ in water containing 0.5% DMSO (v/v) was determined as 1.77×105 M−1. The detection limit of probe L for the analysis of Hg2+ was determined as 21.72ppb. Moreover, probe L can be used for selective sensing of Hg2+ based on the obvious color changes in real samples. Further, the interaction between the probe L and Hg2+ was investigated by 1H NMR titration and the probable structure of probe L-Hg2+ complex was predicted by B3LYP method.

Publisher URL: www.sciencedirect.com/science

DOI: S0020169317313075

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