Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
4 years ago

Simple and rapid synthesis of conducting metallopolymers, their electrochemical characterizations and application in electrochromics

Simple and rapid synthesis of conducting metallopolymers, their electrochemical characterizations and application in electrochromics
Conducting metallopolymers have attracted a great deal of attention due to their multifunctional properties based on presence of metal centers as well as the interactions metal and p-conjugated polymer backbone. Due to their multifunctional properties, conducting metallopolymers have a great potential to use in various technological applications. In this work, starting with Lawesson's reagent and hydroxyl functionalized thiophene, a simple and rapid synthesis method for design conductive metallopolymer is proposed. Structural and electrochemical characterization of trans–bis[O-(thiopheneth-3-yl)(4-methoxyphenyl)dithiophosphonato]nickel(II) (TBTNi) were achieved. Spectroelectrochemical and electrochromic properties of the copolymer of TBTNi with thiophene were investigated.

Publisher URL: www.sciencedirect.com/science

DOI: S0022328X17305429

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