3 years ago

Cobalt-platinum heterometallic clusters containing N-heterocyclic carbene ligands

Cobalt-platinum heterometallic clusters containing N-heterocyclic carbene ligands
The heteronuclear cobalt-platinum cluster [Co2Pt2(IPr)2(μ 2-CO)4(CO)4] can be obtained from the [Pt(IPr)] fragment through an addition reaction with [Co2(CO)8], and with subsequent cluster fragmentation, with [Co4(CO)12] and [Co3(μ 3-CH)(CO)9]; the latter reaction with the methylidyne cluster also afforded another cobalt-platinum cluster [Co4Pt26-C)(IPr)2(μ 2-CO)5(CO)6]. These are the first examples of Co-Pt heteronuclear clusters containing NHC ligands.

Publisher URL: www.sciencedirect.com/science

DOI: S0022328X17304138

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.