Inorganic Chemistry Communication
Inorganic Chemistry Communication
3 years ago

Bimetallic cis-dioxomolybdenum(VI) complex containing hydrazone ligand: Syntheses, crystal structure and catalytic studies

Bimetallic cis-dioxomolybdenum(VI) complex containing hydrazone ligand: Syntheses, crystal structure and catalytic studies
Bimetallic molybdenum(VI) complex [(MoO2)2(slsch)(H2O)2] containing dihydrazone ligand was synthesized by reaction of ligand with MoO2(acac)2 in 1:2M ratio in methanol. The bimetallic complex obtained was characterized by various spectroscopic studies. The structure of complex was assigned using Single Crystal X-ray Crystallography and DFT method. We have also explored the catalytic behavior of complex for oxidation of primary benzylic, aliphatic, allylic, and propargylic alcohols.

Publisher URL: www.sciencedirect.com/science

DOI: S1387700317306330

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