Inorganic Chemistry Communication
Inorganic Chemistry Communication
4 years ago

3-D organic-inorganic hybrid architecture based on Tröger's Base: Synthesis, supramolecular structure, and aggregation-induced emission properties

3-D organic-inorganic hybrid architecture based on Tröger's Base: Synthesis, supramolecular structure, and aggregation-induced emission properties
An organic-inorganic hybrid solid (DMDP)[Hg(SCN)4] (1) (DMDP=2,8-(6H,12H-5,11-methanodibenzo[b,f]diazocineylene)-di(p-ethenyl-N-methyl-pyridinium)) was designed and synthesized. X-Ray structural analysis reveals that it comprises a 3-D interpenetrating superstructure that 1-D inorganic anionic chains {[Hg(SCN)4]2−}∞ penetrates into 2-D organic (DMDP)2+ cationic network. Photoluminescence investigation show that compound 1 exhibits a typical aggregation-induced emission (AIE) properties.

Publisher URL: www.sciencedirect.com/science

DOI: S1387700317307402

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