3 years ago

A new tri-nuclear Ag(I)-MOF as potential energetic materials constructed using (1e)-N′-hydroxy-2-(1H-1,2,4-triazol-1-yl) ethanimidamide and nitrates

A new tri-nuclear Ag(I)-MOF as potential energetic materials constructed using (1e)-N′-hydroxy-2-(1H-1,2,4-triazol-1-yl) ethanimidamide and nitrates
The reaction of silver nitrate with (1e)-N′-hydroxy-2-(1H-1,2,4-triazol-1-yl) ethanimidamide (HTE) at room temperature affords a new 3D metal-organic frameworks, {[Ag3(HTE)2(NO3)2]·NO3}n (1). Single crystal X-ray diffraction analysis reveals that the three silver metal centers are bridged by two HTE ligands and Ag-Ag strong interactions in 1. The bridges provided through the nitrogen atoms on triazole-ring and the nitrogen atoms of the ethanimidamide resulted in a trinuclear units {Ag3(HTE)2} linked metal organic framework (MOF) structure. The MOF is displaying the trinuclear units that are connected via nitrates to give a 3D network. There are free nitrates incorporated in the channels of the MOF.

Publisher URL: www.sciencedirect.com/science

DOI: S1387700317300886

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