Zeitschrift für Anorganische und Allgemeine Chemie
Zeitschrift für Anorganische und Allgemeine Chemie
4 years ago

Iron(II) Complexes with Boron Cluster Anion [B10Cl10]2–: Intermolecular Interactions according to 35Cl NQR Spectroscopy and X-ray Diffraction

Iron(II) Complexes with Boron Cluster Anion [B10Cl10]2–: Intermolecular Interactions according to 35Cl NQR Spectroscopy and X-ray Diffraction
Andrei. A. Gippius, Varvara V. Avdeeva, Elena A. Malinina, Grigorii A. Buzanov, Timofei. E. Demikhov, Irina N. Polyakova†, Eleonora A. Kravchenko, Nikolai T. Kuznetsov
Secondary interactions, in which decachloro-closo-decaborate anions are involved were studied in solvates [Fe(phen)3][B10Cl10]·0.875CH3CN·0.125H2O (1), {[Fe(bipy)3][B10Cl10]}·2Bipy·0.5CH3CN (2), {[Fe(bipy)3]2[B10Cl10]2}·2.25CH3CN (3), and [Fe(bipy)3]3[B10Cl10]3·2CH3CN·H2O (4). Structures 1–4 were determined by X-ray diffraction analysis, and complexes 1–3 were studied using 35Cl NQR spectroscopy. A number of C–H···Cl and p···π interactions between chlorine atoms and delocalized electron density of phenyl rings or C≡N groups of acetonitrile molecules were identified. The results obtained by the two methods were compared and the relative strength of secondary interactions were estimated.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/zaac.201700293

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.