5 years ago

KBaR(BO 3 ) 2 orthoborates (R = REE): Synthesis and study

A. K. Bolatov, M. M. Burkitbaev, V. S. Shevchenko, B. M. Uralbekov, N. G. Kononova, A. E. Kokh


The search for compounds with the formula composition KBaR(BO3)2 has been performed by solid-phase synthesis and differential thermal analysis. The compounds synthesized in this series are KBaPr(BO3)2 and KBaNd(BO3)2, which are isostructural to KBaY(BO3)2, are isotypical to butschliite K2Ca(CO3)2, and crystallize in a trigonal system with space group R3m. The structural characteristics of compounds calculated for the entire series of REEs are given.

Publisher URL: https://link.springer.com/article/10.1134/S0036023617090133

DOI: 10.1134/S0036023617090133

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