KBaR(BO 3 ) 2 orthoborates (R = REE): Synthesis and study
Abstract
The search for compounds with the formula composition KBaR(BO3)2 has been performed by solid-phase synthesis and differential thermal analysis. The compounds synthesized in this series are KBaPr(BO3)2 and KBaNd(BO3)2, which are isostructural to KBaY(BO3)2, are isotypical to butschliite K2Ca(CO3)2, and crystallize in a trigonal system with space group R3m. The structural characteristics of compounds calculated for the entire series of REEs are given.
Publisher URL: https://link.springer.com/article/10.1134/S0036023617090133
DOI: 10.1134/S0036023617090133
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