Chemistry - A European Journal
Chemistry - A European Journal
4 years ago

Ag1Pd1 Nanoparticles–Reduced Graphene Oxide as a Highly Efficient and Recyclable Catalyst for Direct Aryl C−H Olefination

Ag1Pd1 Nanoparticles–Reduced Graphene Oxide as a Highly Efficient and Recyclable Catalyst for Direct Aryl C−H Olefination
Wu Zhang, Qiyan Hu, Xiaowang Liu, Guoliang Wang, Feifan Wang, Qian Li
Ag1Pd1 nanoparticles–reduced graphene oxide (Ag1Pd1-rGO) was used as highly efficient and recyclable catalyst for the chelation-assisted ortho C−H bond olefination of amides with acrylates in good yields with a broad substrate scope. The catalyst can be recovered and reused at least 5 times without losing its activity. A synergistic effect between the Ag and Pd atoms on the catalytic activity was found, and a plausible mechanism for the AgPd-rGO catalyzed C−H olefination was proposed. More information can be found in the Communication by X. Liu, W. Zhang et al. (DOI: 10.1002/chem.201704056).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201704731

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