3 years ago

Di(hydroperoxy)alkane Adducts of Phosphine Oxides: Safe, Solid, Stoichiometric, and Soluble Oxidizing Agents

Di(hydroperoxy)alkane Adducts of Phosphine Oxides: Safe, Solid, Stoichiometric, and Soluble Oxidizing Agents
Janet Blümel, Nattamai Bhuvanesh, Shin Hye Ahn
The most fascinating feature of novel di(hydroperoxy)alkane adducts of phosphine oxides R3PO⋅(HOO)2CR′R“ is that for all substituents R, R′, and R” large single crystals are easily obtained, enabling easy purification and characterization. There are several other advantages, including facile synthesis at ambient temperature, they can be stored on a shelf indefinitely without loss of oxidizing power, and are soluble in organic solvents. More information can be found in the Full Paper by J. Blümel et al. (DOI: 10.1002/chem.201703676).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201704702

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