Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis
5 years ago

Acyl Radicals via Light-Driven Cobalt(I)-Catalysis

Acyl Radicals via Light-Driven Cobalt(I)-Catalysis
Oskar Baka, Dorota Gryko, Jakub Narodowiec, Michał Ociepa
The inside cover picture, provided by Michał Ociepa, Oskar Baka, Jakub Narodowiec, and Dorota Gryko, features a light-driven, cobalt(I)-catalyzed method enabling an easy access to acyl radicals from readily available 2-S-pyridyl thioesters. This novel methodology is suitable for the construction of C−C bonds through the radical acylation of activated olefins. The key steps involve the formation of acyl-cobalt complexes and subsequent photolysis of the Co−C bond. Details of this study can be found in the full paper on pages xxxx-xxxx (M. Ociepa, O. Baka, J. Narodowiec, D. Gryko, Adv. Synth. Catal. 2017, 359, xxxx–xxxx; DOI: 10.1002/adsc.201700913).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adsc.201701271

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.