5 years ago

Acyl Radicals via Light-Driven Cobalt(I)-Catalysis

Acyl Radicals via Light-Driven Cobalt(I)-Catalysis
Oskar Baka, Dorota Gryko, Jakub Narodowiec, Michał Ociepa
The inside cover picture, provided by Michał Ociepa, Oskar Baka, Jakub Narodowiec, and Dorota Gryko, features a light-driven, cobalt(I)-catalyzed method enabling an easy access to acyl radicals from readily available 2-S-pyridyl thioesters. This novel methodology is suitable for the construction of C−C bonds through the radical acylation of activated olefins. The key steps involve the formation of acyl-cobalt complexes and subsequent photolysis of the Co−C bond. Details of this study can be found in the full paper on pages xxxx-xxxx (M. Ociepa, O. Baka, J. Narodowiec, D. Gryko, Adv. Synth. Catal. 2017, 359, xxxx–xxxx; DOI: 10.1002/adsc.201700913).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adsc.201701271

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