Stabilization of Allylic Amine N-Oxide through Cocrystallization with Pyrogallol[4]arene

5 years ago

Stabilization of Allylic Amine N-Oxide through Cocrystallization with Pyrogallol[4]arene

Huan Zhou, Daqiang Yuan, Yiwen Zhang, Kongzhao Su, Zhengbo Han

[2,3]-Meisenheimer rearrangement of active allylic amine N-oxide (ANO) was suppressed by cocrystallization with pyrogallol[4]arene. This work provides not only a new strategy to stabilize active chemicals, but also a unique method to elucidate their structures.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b01136

DOI: 10.1021/acs.cgd.7b01136

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