Inorganic Chemistry
Inorganic Chemistry
5 years ago

Three-Fold-Symmetric Selenium-Donor Metallaboratranes of Cobalt and Nickel

Three-Fold-Symmetric Selenium-Donor Metallaboratranes of Cobalt and Nickel
Ferdinand Belaj, Michael Tüchler, Stefan Holler, Michaela C. Roschger, Karl Kirchner, Luis F. Veiros, Nadia C. Mösch-Zanetti
The selenium-containing ligand K[Tnse] with a [BSe3] donor set has been synthesized, leading to novel cobalt and nickel metallaboratrane complexes with selenium donor atoms. Axial ligands trans to boron are labile toward substitution, leading to chloride, azide, or cationic compounds. The electronic properties were investigated using density functional theory calculations.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01730

DOI: 10.1021/acs.inorgchem.7b01730

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