3 years ago

Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C–H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect

Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C–H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect
Xiaolu Wang, Hongyan Fan, Mengjia Liu, Yuqing Wang, Hongwei Hou, Chao Huang, Jie Wu
Three Cu(I)-based CPs (13) were synthesized and used as heterogeneous catalysts to catalyze direct C−H bond activation reactions of arylalkanes to ketones in aqueous phase under mild conditions. The CPs not only can serve as highly efficient catalysts for the oxidation of hydrocarbons but also present a high regioselectivity due to their unique spatial confinement effect.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02106

DOI: 10.1021/acs.inorgchem.7b02106

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