Crystal Growth & Design
Crystal Growth & Design
4 years ago

A Generalized Avrami Equation for Crystallization Kinetics of Polymers with Concomitant Double Crystallization Processes

A Generalized Avrami Equation for Crystallization Kinetics of Polymers with Concomitant Double Crystallization Processes
Shu-Fen Zou, Rui-Yang Wang, Biao Zuo, Xin-Ping Wang, Bin Fan, Zhi-Qiang Fan, Meng-Fei Hou, Bai-Yu Jiang, Jun-Ting Xu
The kinetic equations for three types of double crystallization processes are derived and compared with that of a single crystallization process. The concept of energy barrier-related “domains” is introduced, which determines the crystallization type. This model can be applied to crystallization kinetics in different polymer systems with concomitant double crystallization processes.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b01016

DOI: 10.1021/acs.cgd.7b01016

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