Understanding the Inhibiting Effect of BTC on CuBTC Growth through Experiment and Modeling

4 years ago

Understanding the Inhibiting Effect of BTC on CuBTC Growth through Experiment and Modeling

Freek Kapteijn, Monique A. van der Veen, Katrin F. Domke, Philipp Schäfer

An increase in the Cu²⁺ concentration leads to an increase in the reaction rate of CuBTC MOF formation, while a high BTC concentration slows down the growth because of the formation of a BTC-overcoordinated CuBTC_x species that only slowly reacts to CuBTC MOF.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00938

DOI: 10.1021/acs.cgd.7b00938

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