Inorganic Chemistry
Inorganic Chemistry
4 years ago

Synthesis and Structural, Electrical, and Magnetic Properties of New Iron–Aluminum Alluaudite Phases β-Na2Ni2M(PO4)3 (M = Fe and Al)

Synthesis and Structural, Electrical, and Magnetic Properties of New Iron–Aluminum Alluaudite Phases β-Na2Ni2M(PO4)3 (M = Fe and Al)
Saïd Obbade, Cécile Rossignol, Douha Harbaoui, Noureddine Amdouni, Moustafa M. S. Sanad, El Kebir Hlil
The orthorhombic crystal structure of Na2Ni2M(PO4)3 (M = Fe, Al), obtained by association of infinite layers [Ni2M(PO4)3]2− to form a three-dimensional anionic framework with different channels running along b⃗ directions, shows interesting electrical, electrochemical, and magnetic properties, with a ferromagnetic to paramagnetic transition at low temperature and linear electrical behavior (Arrhenius law) with activation energies of 0.63 and 0.84 eV for iron and aluminum compounds, respectively.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01880

DOI: 10.1021/acs.inorgchem.7b01880

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