Inorganic Chemistry
Inorganic Chemistry
4 years ago

Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets

Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets
Pierre Thuéry, Jack Harrowfield
The crystal structures of 14 uranyl complexes containing either the trans or cis isomer of 1,4-cyclohexanedicarboxylate, or a mixture of both, have been determined, showing a strong dependence on the experimental conditions, particularly on the organic or metallic counterions present. The complexes formed have dimensionalities in the whole 0−3 range, and three novel examples of interpenetrated two- and three-dimensional networks are reported. Uranyl emission spectra fit with the general trend observed with other polycarboxylate ligands.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02176

DOI: 10.1021/acs.inorgchem.7b02176

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.