3 years ago

Palladium-Catalyzed Aerobic Oxygenation of Allylarenes

Palladium-Catalyzed Aerobic Oxygenation of Allylarenes
Meng Li, Wanqing Wu, Jianxiao Li, Huanfeng Jiang, Chunsheng Li, Jianhua Liao
An efficient and practical protocol for the synthesis of (E)-allylethers from readily available olefins with alcohols or phenols was developed. This aerobic oxidative allylic C–H oxygenation protocol features mild conditions, broad substrate scope, and high atom and step economy, making it a valuable and convenient synthetic method. Notably, molecular oxygen is the sole oxidant in this novel transformation.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01729

DOI: 10.1021/acs.joc.7b01729

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