Journal of Organic Chemistry
Journal of Organic Chemistry
4 years ago

H-Aggregated π-Systems Based on Disulfide-Linked Dimers of Dipyrrolyldiketone Boron Complexes

H-Aggregated π-Systems Based on Disulfide-Linked Dimers of Dipyrrolyldiketone Boron Complexes
Yoshifumi Sasano, Nobuhiro Yasuda, Yasuteru Shigeta, Ryuma Sato, Hiromitsu Maeda
Dipyrrolyldiketone boron complexes linked by a disulfide bond were synthesized, forming H-aggregated dimers assisted by intramolecular π–π and hydrogen-bonding interactions. The conformations of the dimers, with small C–S–S–C dihedral angles, were examined by UV–vis absorption and 1H NMR spectra as well as single-crystal X-ray analysis and theoretical studies.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b02185

DOI: 10.1021/acs.joc.7b02185

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.