Journal of Organic Chemistry
Journal of Organic Chemistry
4 years ago

Design, Synthesis, and Application of Polymer-Supported Silicon-Transfer Agents for Cross-Coupling Reactions with Organolithium Reagents

Design, Synthesis, and Application of Polymer-Supported Silicon-Transfer Agents for Cross-Coupling Reactions with Organolithium Reagents
Minh H. Nguyen, Amos B. Smith, Kevin T. O’Brien
The initial design, synthesis, and validation of polymer-supported siloxane transfer agents have been achieved that permit the direct use of organolithium reagents in the palladium-catalyzed cross-coupling reactions. Through rational design, two generations of polymer support were developed that significantly simplify product purification and the transfer agent recycling.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b02004

DOI: 10.1021/acs.joc.7b02004

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