3 years ago

Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts

Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts
Zoltán Novák, Klára Aradi, Balázs L. Tóth, Zoltán Vincze, Ádám Mészáros
A novel synthetic methodology was developed for the N-arylation of nitroenamine derivatives utilizing diaryliodonium triflates and copper(I) chloride as a catalyst. The procedure enables the easy aryl transfer from the hypervalent species under mild catalytic conditions with unusual heteroatom preference and high efficiency.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01591

DOI: 10.1021/acs.joc.7b01591

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