3 years ago

Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents

Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents
Wei-Can Dai, Zhong-Xia Wang
Reaction of aryltrimethylammonium iodides with arylzinc chlorides in the absence of a transition-metal catalyst to form biaryl compounds was performed under mild conditions. The reaction was suitable for a broad scope of substrates and exhibited good compatibility of functional groups. The Mg2+ ion was demonstrated to markedly promote the reaction. Zincing or Iodeling? Reaction of aryltrimethylammonium iodides with arylzinc reagents in the absence of a transition-metal catalyst was performed. The reaction is applicable to a broad scope of substrates and shows good compatibility of functional groups.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/asia.201701342

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