3 years ago

Visible-light-induced direct oxysulfonylation of alkynes with sulfonyl chlorides and HCl

Visible-light-induced direct oxysulfonylation of alkynes with sulfonyl chlorides and HCl
A mild, practical and efficient strategy to prepare β-keto sulfones has been developed by visible-light-induced reactions. This reaction involved Ir(dtbbpy)(ppy)2PF6-catalyzed direct functionalization of alkynes with sulfonyl chloride and HCl using air as the oxidant. HCl not only acted as a hydrogen source in the proton transfer process, but also played a vital role in the reaction process.

Publisher URL: www.sciencedirect.com/science

DOI: S0040403917312509

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