ACS Catalysis
ACS Catalysis
5 years ago

Coupled Flavin-Iodine Redox Organocatalysts: Aerobic Oxidative Transformation from N-Tosylhydrazones to 1,2,3-Thiadiazoles

Coupled Flavin-Iodine Redox Organocatalysts: Aerobic Oxidative Transformation from N-Tosylhydrazones to 1,2,3-Thiadiazoles
Takuma Kumoi, Maasa Kimura, Tatsuro Ishikawa, Hiroki Iida
A bioinspired two-component redox organocatalyst system using 1,10-bridged flavinium and NH4I was developed to perform environmentally friendly aerobic oxidative ring formation of 1,2,3-thiadiazoles from N-tosylhydrazones and sulfur. The redox organocatalysis of the flavinium promoted the iodine-catalyzed system without the use of any sacrificial reagents, except for environmentally benign molecular oxygen.

Publisher URL: http://dx.doi.org/10.1021/acscatal.7b01535

DOI: 10.1021/acscatal.7b01535

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