3 years ago

Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides

Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides
Takahiro Nishimura, Jun-ichi Fukuda, Miyuki Hatano, Hideki Yorimitsu, Midori Nagamoto
Hydroxoiridium complexes efficiently catalyzed the hydroarylation of alkynes and bicycloalkenes with N-sulfonylbenzamides via C–H activation to give the corresponding ortho-alkenylation and alkylation products in high yields.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02950

DOI: 10.1021/acs.orglett.7b02950

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