3 years ago

Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant

Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant
Duy N. Mai, Jordan D. Galloway, Ryan D. Baxter
A new method for silver-catalyzed Minisci reactions using Selectfluor as a mild oxidant is reported. Heteroarenes and quinones both participate in radical C–H alkylation and arylation from a variety of carboxylic and boronic acid radical precursors. Several oxidatively sensitive and highly reactive radical species are successful, providing structures that are challenging to access by other means.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b02706

DOI: 10.1021/acs.orglett.7b02706

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