3 years ago

Palladium-Catalyzed Cross-Coupling of Nitroarenes

Palladium-Catalyzed Cross-Coupling of Nitroarenes
Yang Yang
Pd at the crossroads: The palladium-catalyzed cross-coupling of nitroarenes has eluded chemists for decades. Recently, the first palladium-catalyzed Suzuki–Miyaura and Buchwald–Hartwig cross-couplings of nitroarenes were reported. Mechanistically, this process involves the challenging oxidative addition of LPd0 into the Ar−NO2 bond. This process features a broad substrate scope with respect to both the nitroarene and the nucleophilic coupling partners.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201708940

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