3 years ago

Structure, Electronics and Reactivity of Ce(PNP) Complexes

Structure, Electronics and Reactivity of Ce(PNP) Complexes
Eric J. Schelter, Alexander V. Zabula, Thibault Cheisson, Patrick J. Carroll, Yusen Qiao, Oleg V. Ozerov, Brian C. Manor, Alex J. Kosanovich
The coordination chemistry of complexes featuring a PNP ligand framework and the redox active lanthanide ion, cerium(III), was initiated. The cerium(III) ion induced the transformation of one of the phosphino donor arms at a parent PNP ligand into a new phosphido functionality. The Ce−PNP systems were also employed for C−C bond-forming reactions and the molecular structures of Ce−PNP complexes were studied both in solution and in the solid state. More information can be found in the Full Paper by O. V. Ozerov, E. J. Schelter et al. (DOI: 10.1002/chem.201703174).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201704200

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