3 years ago

Denticity and Mobility of the Carbonate Groups in AMCO3F Fluorocarbonates: A Study on KMnCO3F and High Temperature KCaCO3F Polymorph

Denticity and Mobility of the Carbonate Groups in AMCO3F Fluorocarbonates: A Study on KMnCO3F and High Temperature KCaCO3F Polymorph
Jean-Marie Tarascon, Gwenaelle Rousse, Hania Ahouari, Nadir Recham, Artem M. Abakumov, Vladimir Pomjakushin
The crystal structures of a novel KMnCO3F fluorocarbonate and high temperature polymorph of KCaCO3F have been determined. Reversible first order phase transition is detected between the low temperature and high temperature forms of KCaCO3F. The correlation between the carbonate groups’ denticity, their mobility, and cation size variance is discussed.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01926

DOI: 10.1021/acs.inorgchem.7b01926

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