3 years ago

Ion-selective properties of 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L 1 ) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L 2 ). Crystal structure of complexes [CdI 2 (μ-L 1 )] 2 , [CdBr 2 (μ-L 1 )] 2 · C 2 H 5 OH, and [Cd(L 2 ) 2 (H 2 O) 2 ][Cd 2 I 6 ]


Ion-selective properties of polymeric plasticized membranes of ion-selective electrodes based on 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L1) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L2) toward certain bivalent metal cations has been studied. It has been shown that podand L2 can be used as a sensor component of polymeric plasticized membrane of ion-selective electrode for quantitative determination of Pb2+ ions in aqueous solutions. The structure of complexes [CdI2(μ-L1)]2, [Cd(μ-L1)Br2]2 · C2H5OH, and [Cd(L2)2(H2O)2][Cd2I6] has been studied by X-ray diffraction and IR spectroscopy.

Publisher URL: https://link.springer.com/article/10.1134/S0036023617100102

DOI: 10.1134/S0036023617100102

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