3 years ago

Ruthenium(0) Catalyzed Cycloaddition of 1,2-Diols, Ketols or Diones via Alcohol-Mediated Hydrogen Transfer

Ben W. H. Turnbull, Hiroki Sato, Michael Joseph Krische, Keisuke Fukaya
Merging the characteristics of transfer hydrogenation and carbonyl addition, a broad new class of ruthenium(0) catalyzed cycloadditions has been developed. Fused or bridged bicyclic ring systems are accessible in a redox-independent manner in C-C bond forming hydrogen transfer reactions of diols, α-ketols or 1,2-diones with diverse unsaturated reactants.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201709916

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