3 years ago
Silver and Palladium Cocatalyzed Carbonylative Activation of Benzotriazoles to Benzoxazinones under Neutral Conditions

Zechao Wang, Zhiping Yin, Xiao-Feng Wu
A novel and efficient method for the carbonylative activation of benzotriazoles to benzoxazinones has been developed. By using a silver and palladium bimetallic catalyst system, a broad range of benzotriazoles were transformed into the corresponding benzoxazinones in moderate to good yields with excellent functional group tolerance. Notably, this procedure proceeds under neutral conditions.
Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b03184
DOI: 10.1021/acs.orglett.7b03184
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