3 years ago

Carbon-Encapsulated Sn@N-Doped Carbon Nanotubes as Anode Materials for Application in SIBs

Carbon-Encapsulated Sn@N-Doped Carbon Nanotubes as Anode Materials for Application in SIBs
Hua-kun Liu, Jia-zhao Wang, Shu-lei Chou, Hai-peng Guo, Yuanfu Deng, Yuyang Hou, Guohua Chen, Boyang Ruan, Qiannan Liu
Carbon-encapsulated Sn@N-doped carbon tubes with submicron diameters were obtained via the simple reduction of C@SnO2@N-doped carbon composites that were fabricated by a hydrothermal approach. Sn nanoparticles encapsulated in carbon layers were distributed uniformly on the surfaces of the N-doped carbon nanotubes. The electrochemical performances of the composites were systematically investigated as anode materials in sodium-ion batteries (SIBs). The composite electrode could attain a good reversible capacity of 398.4 mAh g–1 when discharging at 100 mA g–1, with capacity retention of 67.3% and very high Coulombic efficiency of 99.7% over 150 cycles. This good cycling performance, when compared to only 17.5 mAh g–1 delivered by bare Sn particles prepared via the same method without the presence of N-doped carbon, could be mainly ascribed to the uniform distribution of the precursor SnO2 on the substrate of N-doped carbon tubes with three-dimensional structure, which provides more reaction sites to reduce the diffusion distance of Na+, further facilitating Na+-ion diffusion and relieves the huge volume expansion during charging/discharging. These outcomes imply that such a Sn/C composite would provide more options as an anode candidate for SIBs.

Publisher URL: http://dx.doi.org/10.1021/acsami.7b10085

DOI: 10.1021/acsami.7b10085

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