3 years ago

Optimization of process parameters for determination of trace Hazardous dyes from industrial wastewaters based on nanostructures materials under ultrasound energy

Optimization of process parameters for determination of trace Hazardous dyes from industrial wastewaters based on nanostructures materials under ultrasound energy
In this study, ultrasound-assisted dispersive solid phase micro-extraction based on nanosorbent namely silver-zinc oxide nanoparticles loaded on activated carbon (Ag-ZnO-NP-AC) combined with derivative spectrophotometry method for the simultaneous pre-concentration and determination of Methyl Green (MG) and Rose Bengal (RB) dyes in water and industrial wastewater. Characterized sorbent by field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX), particle-size distribution (PSD), Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD) and Transmission electron microscopy (TEM) analysis with superior adsorption capacity was applied in ultrasound assisted dispersive-solid-phase micro-extraction (UA-DSPME) methodology. pH, sorbent mass, ultrasonication time, and eluent volume influence and contribution on response correspond to simultaneous pre-concentration and determination of MG and RB were optimized by response surface methodology (RSM) and results were compared with the experimental values. Under the optimal conditions (UA-DSPME), the enrichment factors (EFs) were 93.89 and 97.33 for the MG and RB dyes, respectively. The limits of detection were 2.14 and 2.73ngmL−1 and the limit of quantification were 7.15 and 9.09ngmL−1 for MG and RB, respectively. The analytes can be determined over 10–2000ngmL−1 with recoveries between 90.8% to 97.7% and RSDs less than 3.6%. The developed method due to simplicity and rapidity is able successful for repeatable and accurate monitoring of under study analytes from complicated matrices.

Publisher URL: www.sciencedirect.com/science

DOI: S135041771730319X

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