3 years ago

Toward Molecular Recognition of REEs: Comparative Analysis of Hybrid Nanoadsorbents with the Different Complexonate Ligands EDTA, DTPA, and TTHA

Toward Molecular Recognition of REEs: Comparative Analysis of Hybrid Nanoadsorbents with the Different Complexonate Ligands EDTA, DTPA, and TTHA
Vadim G. Kessler, Gulaim A. Seisenbaeva, Elizabeth Polido Legaria, Michail Samouhos
A broad comparative study of single-crystal structures of the complexes between REEs and nongrafted complexonates at neutral and acidic pHs led to a molecular understanding of their individual modes of action. EDTA-derived nanoadsorbents combine concerted action and chelation, whereas the latter is the preferential coordination mechanism for DTPA- and TTHA-derived nanoadsorbents.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02056

DOI: 10.1021/acs.inorgchem.7b02056

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