Catalysis Science and Technology
Catalysis Science and Technology
5 years ago

Catalytic carbonyl hydrosilylations via a titanocene borohydride-PMHS reagent system

Catalytic carbonyl hydrosilylations via a titanocene borohydride-PMHS reagent system
Robert A. Flowers II, Godfred D. Fianu, Kyle C. Schipper
Catalytic amounts of titanocene(III) borohydride, generated under mild conditions from commercially available titanocene dichloride, in concert with a stoichiometric hydride source is shown to effectively reduce aldehydes and ketones to their respective alcohols in aprotic media.

Publisher URL: http://feeds.rsc.org/~r/rss/cy/~3/Zi6Zjusn90M/C7CY01088E

DOI: 2017/CY/C7CY01088E

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